Chirality induction by E-Z photoisomerization in [2,2]paracyclophane-bridged azobenzene dimer
Chirality induction by E-Z photoisomerization in [2,2]paracyclophane-bridged azobenzene dimer
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DOI：
10.1016/j.tetlet.2012.10.121
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发表时间：
2013-01-09
影响因子：
1.8
通讯作者：
Tamaoki, Nobuyuki
中科院分区：
文献类型：
--
作者：
Hashim, P. K.;Basheer, Meethale C.;Tamaoki, Nobuyuki
我们设计并合成了一种新型的前手性分子，在[2，2]对环番分子中嵌入了两个偶氮苯基团，并通过E-Z光异构化反应显示了手性诱导作用。我们还分别通过辐照和回流实现了非对称性的开关。(C)2012爱思唯尔有限公司。保留所有权利。
We designed and synthesized a new prochiral molecule in which two azobenzene moieties were embedded in [2,2]paracyclophane and showed the chirality induction by E-Z photoisomerization. We also demonstrated the on/off switching of asymmetry by irradiation and reflux respectively. (C) 2012 Elsevier Ltd. All rights reserved.