Highly Selective Anionic Counterion-based Fluorescent Sensor for Hg(2+) by Grafted Conjugated Polyelectrolytes.

Highly Selective Anionic Counterion-based Fluorescent Sensor for Hg(2+) by Grafted Conjugated Polyelectrolytes.
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DOI:
10.1002/marc.201000419
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发表时间:
2010-12
影响因子:
4.6
通讯作者:
Zhiyong Zhang;Quli Fan;Pengfei Sun;Lulin Liu;Xiaomei Lu;Bo Li;Yiwu Quan;Wei Huang
Zhiyong Zhang;Quli Fan;Pengfei Sun;Lulin Liu;Xiaomei Lu;Bo Li;Yiwu Quan;Wei Huang
中科院分区:
化学3区
文献类型:
--
作者:
Zhiyong Zhang;Quli Fan;Pengfei Sun;Lulin Liu;Xiaomei Lu;Bo Li;Yiwu Quan;Wei Huang

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首次合成并表征了接枝共轭聚电解质。该聚合物显示出用于创建Hg(2+)传感器的方便和有效的协议的性质。这种新材料的独特性质来自于阴离子的反离子性质,没有外部辅助因子,并赋予荧光探针中汞离子的高选择性和快速检测。该概念可能被应用于创建用于监测其他离子的新传感器。
Grafted conjugated polyelectrolytes were synthesized for the first time and characterized. The polymers demonstrated properties of a convenient and efficient protocol for creating Hg(2+) sensors. The unique character of the new material comes from an anionic counterion nature with no external cofactors, and imparts high selectivity and fast detection for mercury ion in a fluorescence probe. The concept may be potentially applied to create new sensors for monitoring other ions.