2,3,6,7-Tetraamino-9,9-bis(2-ethylhexyl) fluorene: New multifunctional monomer for soluble ladder-conjugated molecules and polymers

2,3,6,7-Tetraamino-9,9-bis(2-ethylhexyl) fluorene: New multifunctional monomer for soluble ladder-conjugated molecules and polymers
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2,3,6,7-四氨基-9,9-双(2-乙基己基)芴:用于可溶性梯状共轭分子和聚合物的新型多功能单体

DOI:
10.1021/ol801081w
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发表时间:
2008-07-03
期刊:
影响因子:
5.2
通讯作者:
Qian, Xuhong
Qian, Xuhong
中科院分区:
化学1区
文献类型:
--
作者:
Li, Xichuan;Xiao, Yi;Qian, Xuhong

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2,3,6,7-四氨基-9,9-双(2-乙基己基)芴(TABEF)作为一种新型多功能梯型共轭分子和聚合物单体,通过六步程序高效合成,总产率为30%。还合成并初步研究了两种基于TABEF结构单元的异构梯化合物。
2,3,6,7-Tetraamino-9,9-bis(2-ethylhexyl)fluorene (TABEF), as a new multifunctional monomer for ladder-type conjugated molecules and polymers, was efficiently synthesized via a six-step procedure with an overall yield of 30%. Two isomeric ladder compounds based on TABEF building blocks were also synthesized and preliminarily studied.