Development of a Hydrazine-Catalyzed Carbonyl-Olefin Metathesis Reaction
Development of a Hydrazine-Catalyzed Carbonyl-Olefin Metathesis Reaction
复制标题
DOI：
10.1055/s-0039-1689924
复制
发表时间：
2019-10-01
期刊：
影响因子：
2
通讯作者：
Lambert, Tristan H.
中科院分区：
文献类型：
--
作者：
Lambert, Tristan H.
羰基-烯烃复分解反应是有机合成中一个潜在的强有力的反应。然而，近年来，这种情况已经开始改变，最明显的是引入了几种不同的催化技术。这些新的策略之一，肼催化剂和一个新的[3+2]的双键复分解范例的基础上的发展，在这里讨论。首先，阶段设置与羰基烯烃复分解的一些潜在的应用和讨论的替代策略，这个有趣的反应的描述。
Carbonyl-olefin metathesis is a potentially powerful yet underexplored reaction in organic synthesis. In recent years, however, this situation has begun to change, most notably with the introduction of several different catalytic technologies. The development of one of those new strategies, based on hydrazine catalysts and a novel [3+2] paradigm for double bond metathesis, is discussed herein. First, the stage is set with a description of some potential applications of carbonyl-olefin metathesis and a discussion of alternative strategies for this intriguing reaction.