Conjugated polymers for photocatalysis.

Conjugated polymers for photocatalysis.
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DOI:
10.1021/jp071096n
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发表时间:
2007-06
期刊:
The journal of physical chemistry. B
影响因子:
--
通讯作者:
B. Muktha;G. Madras;T. Row;U. Scherf;S. Patil
B. Muktha;G. Madras;T. Row;U. Scherf;S. Patil
中科院分区:
其他
文献类型:
--
作者:
B. Muktha;G. Madras;T. Row;U. Scherf;S. Patil

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首次研究了共轭聚合物的光催化性能。研究了茜素S、茜素G、橙子G、雷马唑艳蓝等纺织染料在紫外光照射下的降解。实验结果表明,在相同条件下,共轭聚合物的光催化活性明显高于Degussa P-25。通过光致发光、紫外-可见光和红外光谱对光催化反应前后的共轭聚合物进行了表征。并对苯酚的降解进行了研究,探讨了降解的反应途径。
The photocatalytic properties of the conjugated polymers have been investigated for the first time. Degradation of various textile dyes such as Alizarin S, Alizarin G, Orange G, and Remazol brilliant blue were studied under UV radiation. The experimental data indicated that the photocatalytic activity of the conjugated polymers was significantly higher than that of Degussa P-25 under similar conditions. The conjugated polymers were characterized by photoluminescent, UV-visible, and IR spectroscopies before and after photocatalytic reactions. The degradation of phenol was also carried out to study the reaction pathway of degradation.