THE SYNTHESIS AND STABILITY OF ACYL RADICALS - SOME REACTIONS OF DIACYL DIIMIDES
THE SYNTHESIS AND STABILITY OF ACYL RADICALS - SOME REACTIONS OF DIACYL DIIMIDES
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DOI：
10.1021/ja01580a029
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发表时间：
1957-01-01
影响因子：
15
通讯作者：
CRAMER, R
中科院分区：
文献类型：
--
作者：
CRAMER, R
酰基自由基的反应单位似乎低于100，而不是分解为一氧化碳和烷基自由基。也有证据表明，一氧化碳能迅速与简单的烷基结合，生成酰基。这些结论是基于对酰基自由基的检验：(1)一些二酰基二亚胺的解体；(2)烷基自由基从醛中提取氢；(3)烷基自由基加成一氧化碳。文献中报道的理论和实验工作也给予了支持。
Acyl radicals appear to react as units below about 100 rather than disintegrating to carbonmonoxide and alkyl radicals. There is alsoevidence that carbon monoxide rapidly combines with simple alkyl radicals to yield acyl radicals. These conclusions are based on an examination of acyl radicals derived by:(1) disintegration of some diacyl diimides,(2) hydro-gen abstraction from aldehydes by alkyl radicals and (3) carbon monoxide addition by alkyl radicals. Support is also given by theoretical and experimental work which has been reported in the literature.