Dissociation rate of hot benzene
Dissociation rate of hot benzene
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DOI：
10.1063/1.481774
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发表时间：
2000-06
影响因子：
4.4
通讯作者：
Shang‐Ting Tsai;Chihkai Lin;Yuan‐Pern Lee;C. Ni
中科院分区：
文献类型：
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作者：
Shang‐Ting Tsai;Chihkai Lin;Yuan‐Pern Lee;C. Ni
在无碰撞条件下，用多质量离子成像技术测量了苯和d 6-苯的解离速率。苯和d 6-苯的值分别为1±0.2×105 s-1和5±1×104 s-1，内能为618 kJ/mol。内能为483 kJ/mol的苯的解离速率太慢而无法测量，解离速率的上限估计为3×103 s−1。
The dissociation rate of benzene and d6-benzene were measured under collision-free condition by multimass ion imaging techniques. The value of 1±0.2×105 s−1 and 5±1×104 s−1 were obtained for benzene and d6-benzene, respectively, with internal energy of 618 kJ/mol. The dissociation rate of benzene with internal energy of 483 kJ/mol was too slow to be measured, and the upper limit of the dissociation rate was estimated to be 3×103 s−1.