THE THERMODYNAMICS OF ELECTROLYTES AT HIGHER CONCENTRATION
THE THERMODYNAMICS OF ELECTROLYTES AT HIGHER CONCENTRATION
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DOI：
10.1021/j150519a007
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发表时间：
1954-01-01
影响因子：
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通讯作者：
WICKE, E
中科院分区：
文献类型：
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作者：
EIGEN, M;WICKE, E
乔治·斯卡查德（马萨诸塞州理工学院）。马祖尔博士已经证明，与莱因霍尔德的结论的偏差非常小。在我看来，对于测量这些势的常规方法，它们将完全为零。同一性的必要条件是：电位计保持在恒定的温度下，如果直接比较，则两个金属热梯度是在与等温池相同的金属中形成的，如果用量热测量的热系数进行比较，则两个金属热梯度都是在同一金属中形成的。
DISCUSSIONGeorge Scatchard (Massachusetts Institute of Technology).—Dr. Mazur has shown that the deviations from Reinhold’s conclusions are very small. It seems to me that they will be identically zero for the normal method of meas-uring these potentials. The necessary conditions for identity are that the potentiometer remain at constant temperature and that the two metallic thermal gradients be made in the same metals as in the isothermal cells if the comparison is made directly, or the two'metallic thermal gradients both be made in the same metal if the comparison is made with thermal coefficients from calorimetric measure-ments.