A facile one-pot method for synthesis of single phase Co2C with magnetic properties

A facile one-pot method for synthesis of single phase Co2C with magnetic properties
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一种简便的一锅法合成具有磁性的单相Co2C

DOI:
10.1016/j.matlet.2020.127783
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发表时间:
2020-07
期刊:
影响因子:
3
通讯作者:
Yong Yang
Yong Yang
中科院分区:
材料科学3区
文献类型:
--
作者:
Xianfeng Shen;Tianfu Zhang;HaiYun Suo;Lai Yan;Lichun Huang;Chenwei Ma;Linge Li;Xiaodong Wen;Yongwang Li;Yong Yang

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Cobalt carbide nanoparticles including Co2C and Co3C attract great interest as magnetic materials due to their large coercivities and high saturation magnetization. However, it’s hard to obtain the pure phase Co2C with good magnetic properties. A facile method to synthesize the pure phase ferromagnetic Co2C via a one-step polyol reduction process is developed. The crystal structure, morphology and composition of Co2C nanoparticles are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Saturation magnetization and coercivity of the Co2C measured at 300 K are 13.6 emu g−1and 0.58 kOe, respectively. The carbon contents, particle size and morphology of the Co2C are responsible for the large magnetization and high coercivity. This work will provide a strategy to synthesize pure metal carbides for applications in magnetic fields or energy materials.
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