Intramolecular photocycloaddition of dioxenones with alkynes: formation of secondary photoproducts from cyclobutene photoadducts.

Intramolecular photocycloaddition of dioxenones with alkynes: formation of secondary photoproducts from cyclobutene photoadducts.
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二恶烯酮与炔烃的分子内光环加成:从环丁烯光加合物形成次级光产物。

DOI:
10.1021/ol047795p
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发表时间:
2005
期刊:
Organic letters.
影响因子:
--
通讯作者:
McLaughlin,EmilyC
McLaughlin,EmilyC
中科院分区:
--
文献类型:
--
作者:
Winkler,JeffreyD;McLaughlin,EmilyC

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Intramolecular photocycloaddition of4leads to the formation of cyclobutene photoadduct5. Secondary photoreaction of5then affords either cyclobutane19or the bridged product7, as a function of R (H or TMS).