Novel iodinated diterpenes from a marine cyanobacterium and red alga assemblage

Novel iodinated diterpenes from a marine cyanobacterium and red alga assemblage
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DOI:
10.1021/ol035620u
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发表时间:
2003-10-30
期刊:
影响因子:
5.2
通讯作者:
Paul, VJ
Paul, VJ
中科院分区:
化学1区
文献类型:
--
作者:
Williams, PG;Yoshida, WY;Paul, VJ

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[图表]塔西哈里德A和B是从一种海洋蓝藻和一种未知的红藻中分离出来的,这种蓝藻属于丛枝藻属。用光谱学方法确定了这些二萜化合物的结构和相对立体化学结构。除了具有新颖的笼状结构外,它还是自然界中唯一的碘化二萜类化合物。
[GRAPHICS]Tasihalides A and B have been isolated from an assemblage of a marine cyanobacterium, belonging to the genus Symploca, and an unidentified red alga. The gross structures and relative stereochemistries of these diterpenes were elucidated by spectroscopic means. In addition to possessing a novel cage structure, the tasihalides represent the only examples of iodinated diterpenes in nature.