From molecular catalysts to nanostructured materials skeleton catalysts
From molecular catalysts to nanostructured materials skeleton catalysts
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DOI：
10.1351/pac-con-11-10-28
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发表时间：
2012-04
影响因子：
1.8
通讯作者：
N. Asao;T. Jin;Shinya Tanaka;Yoshinori Yamamoto
中科院分区：
文献类型：
--
作者：
N. Asao;T. Jin;Shinya Tanaka;Yoshinori Yamamoto
使用Au，Pd和Cu纳米多孔骨架催化剂和这些催化剂和相应的众所周知的均相分子催化剂之间的反应性差异的分子转化进行了描述。纳米多孔骨架催化剂（例如，PdNPore）可以通过相应的含Pd合金PdxM1yM2z的去合金化来制造。
Molecular transformations using Au, Pd, and Cu nanoporous skeleton catalysts and the reactivity difference between those catalysts and the corresponding well-known homogeneous molecular catalysts are described. Nanoporous skeleton catalysts (e.g., PdNPore) can be fabricated through dealloying of the corresponding Pd-containing alloy PdxM1yM2z.