Lewis acid induced tandem Diels-Alder reaction/ring expansion as an equivalent of a [4+3] cycloaddition
Lewis acid induced tandem Diels-Alder reaction/ring expansion as an equivalent of a [4+3] cycloaddition
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DOI：
10.1021/ja039908q
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发表时间：
2004-03-10
影响因子：
15
通讯作者：
Dai, X
中科院分区：
文献类型：
--
作者：
Davies, HML;Dai, X
氯化铝诱导环戊二烯和 α,β-不饱和醛之间的反应导致立体选择性形成正式的 [4 + 3] 环加成产物。该反应通过串联狄尔斯-阿尔德反应/扩环进行。
Aluminum chloride induced reaction between cyclopentadiene and α,β-unsaturated aldehydes results in the stereoselective formation of the products of a formal [4 + 3] cycloaddition. The reaction proceeds by a tandem Diels−Alder reaction/ring expansion.