A supramolecular-hydrogel-encapsulated hemin as an artificial enzyme to mimic peroxidase
A supramolecular-hydrogel-encapsulated hemin as an artificial enzyme to mimic peroxidase
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DOI：
10.1002/anie.200700404
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发表时间：
2007-01-01
影响因子：
16.6
通讯作者：
Xu, Bing
中科院分区：
文献类型：
--
作者：
Wang, Qigang;Yang, Zhimou;Xu, Bing
（图所示）伪造：利用超分子水凝胶作为人工酶的结构组分，为仿生催化剂的开发提供了一条新的、有用的途径。在甲苯中，包封在这种水凝胶中的氯化血红素达到了大约60%的辣根过氧化物酶的新生催化活性。水凝胶中血红素的活性是游离血红素的387.1倍。©2007 Wiley-VCH Verlag GmbH & Co. KGaA。
(Figure Presented) Faking it: The use of a supramolecular hydrogel as the structural component of artificial enzymes provides a new and useful approach to the development of biomimetic catalysts. In toluene, hemin chloride encapsulated in such a hydrogel achieves about 60% nascent catalytic activity of horseradish peroxidase. Additionally, the activity of hemin in the hydrogel is 387.1 times greater than that of free hemin. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.