N-Confused Porphine
N-Confused Porphine
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DOI：
10.1002/ejoc.200500485
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发表时间：
2005-09
影响因子：
2.8
通讯作者：
Tatsuki Morimoto;S. Taniguchi;A. Osuka;H. Furuta
中科院分区：
文献类型：
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作者：
Tatsuki Morimoto;S. Taniguchi;A. Osuka;H. Furuta
通过[3+1]偶联反应，首次合成了一种含氮杂卟啉骨架（NC-卟啉）。一个完全平面的内部3 H互变异构体的形式被发现在晶体中，和分子包装显示出类似于正常的卟啉的三明治人字形结构，而一些光谱性质表明系统的取代基效应的meso-苯基上的N-混乱的卟啉。（© Wiley-VCH Verlag GmbH & Co. KGaA，69451魏因海姆，德国，2005）
A skeleton of N-confused porphyrin (NC-porphine) has been synthesized for the first time, through a [3+1] coupling reaction. A completely planar inner 3H tautomeric form was found in the crystals, and the molecular packing shows a sandwich herringbone structure similar to that of normal porphine, whilst some of the spectroscopic properties demonstrate systematic substituent effects by the meso-phenyl groups on the N-confused porphyrin. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)