Chukvelutilides A-F, phragmalin limonoids from the stem barks of Chukrasia tabularis var. velutina

Chukvelutilides A-F, phragmalin limonoids from the stem barks of Chukrasia tabularis var. velutina
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DOI:
10.1016/j.tet.2009.02.046
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发表时间:
2009-04-25
期刊:
影响因子:
2.1
通讯作者:
Kong, Ling-Yi
Kong, Ling-Yi
中科院分区:
化学3区
文献类型:
--
作者:
Luo, Jun;Wang, Jun-Song;Kong, Ling-Yi

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Chukvelutilides A-F(1-6)是从Chukrasia tabularis var.天鹅绒。这些化合物被认为具有三个或四个碳烯醇化的酰基取代基在C-15通过一个合理的生物合成的起源。化合物1的结构经X-射线单晶衍射证实。(C)2009爱思唯尔有限公司版权所有。
Chukvelutilides A-F (1-6), a new class of C-15-acyl phragmalin type limonoids, featuring a C-16/C-30 delta-lactone ring, were isolated from Chukrasia tabularis var. velutina. These compounds are suggested to possess a three- or four-carbon enolized acyl substituent at C-15 through a plausible biosynthetic origin. Their structures were elucidated by extensive spectroscopic means, and that of 1 was confirmed by single-crystal X-ray diffraction. (C) 2009 Elsevier Ltd. All rights reserved.