Synthesis and selective transformation of nitrogen-containing compounds via radical pathways
Synthesis and selective transformation of nitrogen-containing compounds via radical pathways
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DOI：
10.1016/s1631-0748(02)01427-3
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发表时间：
2002-10-01
影响因子：
1.6
通讯作者：
Gastaldi, S
中科院分区：
文献类型：
--
作者：
Bertrand, M;Feray, L;Gastaldi, S
本文介绍了本研究组对自由基方法学的发展及其在含氮化合物的合成和反应性中的应用的最新贡献。首先讨论了涉及硫中心自由基的几个级联过程的范围，然后讨论了自由基加成的合成潜力。的C=N键介导的三乙基硼烷和二乙基锌进行了检查。特别关注的是1，3-立体诱导的角度不对称合成。
This account presents the recent contribution of our group to the development of radical methodologies, and their application to the synthesis and the reactivity of nitrogen-containing compounds. The scope of several cascade processes involving sulphur-centred radicals is discussed first, then the synthetic potential of radical additions. to C=N bonds mediated by triethylborane and diethylzinc is examined. Special attention is given to 1,3-stereoinduction in the perspective of enantioselective synthesis.