Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to α, β-unsaturated pyridylsulfones
Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to α, β-unsaturated pyridylsulfones
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DOI：
10.1039/b508142d
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发表时间：
2005-01-01
影响因子：
4.9
通讯作者：
Carretero, JC
中科院分区：
文献类型：
--
作者：
Mauleón, P;Carretero, JC
描述了通过Rh催化的手性催化剂介导的烯基硼酸与β，β-二取代的α，β-不饱和2-吡啶基砜的共轭加成，高对映选择性地构建全碳季立体中心。
The highly enantioselective construction of all-carbon quaternary stereogenic centres via Rh-catalyzed Chiraphos-mediated conjugate addition of alkenylboronic acids to beta,beta-disubstituted alpha,beta-unsaturated 2-pyridylsulfones is described.