The effect of vibrational excitation (3≤v‘≤19) on the reaction Na2 (v‘)+Cl→NaCl+Na*
The effect of vibrational excitation (3≤v‘≤19) on the reaction Na2 (v‘)+Cl→NaCl+Na*
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DOI：
10.1063/1.463271
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发表时间：
1992-12
影响因子：
4.4
通讯作者：
P. Dittmann;F. Pesl;J. Martin;G. Coulston;G. He;K. Bergmann
中科院分区：
文献类型：
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作者：
P. Dittmann;F. Pesl;J. Martin;G. Coulston;G. He;K. Bergmann
使用激光诱导荧光或相干布居转移研究了振动激发 3≤v'≤19 下化学发光通道总积分截面的变化，这是一种利用两个连续激光器延迟相互作用来填充振动激发能级的新方法。每个振动级别横截面随着 v‘ 增加约 0.76%。结果与相空间计算的结果以及简单曲线交叉模型的结果一致。
The variation of the total integral cross section for the chemiluminescent channel with the vibrational excitation 3≤v‘≤19 is investigated using laser‐induced fluorescence or coherent population transfer, a new method employing delayed interaction with two cw lasers to populate vibrationally excited levels. The cross section increases with v‘ by about 0.76% per vibrational level. The results are in agreement with the results of phase‐space calculations, as well as with those from simple curve crossing models.