Highly energy- and time-efficient synthesis of porous triazine-based framework: microwave-enhanced ionothermal polymerization and hydrogen uptake
Highly energy- and time-efficient synthesis of porous triazine-based framework: microwave-enhanced ionothermal polymerization and hydrogen uptake
复制标题
DOI：
10.1039/c0jm01392g
复制
发表时间：
2010-07
影响因子：
--
通讯作者：
Wang Zhang;Cun Li;Yupeng Yuan;L. Qiu;A. Xie;Yuhua Shen;Junfa Zhu
中科院分区：
文献类型：
--
作者：
Wang Zhang;Cun Li;Yupeng Yuan;L. Qiu;A. Xie;Yuhua Shen;Junfa Zhu
采用一种新型的微波（MW）增强高温离子热聚合方法合成了一种共价三嗪基框架（CTF）。通过这种微波增强离子热方法，能够在几十分钟内轻松获得具有高比表面积（高达2390平方米/克）和高氢吸附容量（在1巴和77 K下高达1.78 wt%）的无定形CTF样品。
A covalent triazine-based framework (CTF) was synthesized by using a novel microwave (MW)-enhanced high-temperature ionothermal polymerization method. Amorphous CTF samples with high surface areas (up to 2390 m2 g−1) and high hydrogen adsorption capacities (up to 1.78 wt% at 1 bar and 77 K) could be easily obtained in tens of minutes by using such a MW-enhanced ionothermal method.