Kolbe carbon-carbon coupling electrosynthesis using solid-supported bases
Kolbe carbon-carbon coupling electrosynthesis using solid-supported bases
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DOI：
10.1021/jo801016f
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发表时间：
2008-09-05
影响因子：
3.6
通讯作者：
Tajima, Toshiki
中科院分区：
文献类型：
--
作者：
Kurihara, Hitoshi;Fuchigami, Toshio;Tajima, Toshiki
我们开发了一种基于羧酸作为底物与固体支撑碱之间的酸碱反应的新型Kolbe碳-碳耦合电合成电解体系。在此基础上，成功地进行了各种羧酸的柯尔贝电解，以中等至优异的产率提供相应的均偶联产物。
We have developed a novel electrolytic system for Kolbe carbon-carbon coupling electrosynthesis based on the acid-base reaction between carboxylic acids as a substrate and solid-supported bases. On the basis of the electrolytic system, Kolbe electrolysis of various carboxylic acids was successfully carried out to provide the corresponding homocoupling products in moderate to excellent yields.