1997 CANADIAN SOCIETY FOR CHEMISTRY AWARD LECTURE RING-OPENING POLYMERIZATION (ROP) OF STRAINED METALLOCENOPHANES : THE DISCOVERY AND DEVELOPMENT OF A NEW ROUTE TO HIGH MOLECULAR WEIGHT POLY(METALLOCENES)
1997 CANADIAN SOCIETY FOR CHEMISTRY AWARD LECTURE RING-OPENING POLYMERIZATION (ROP) OF STRAINED METALLOCENOPHANES : THE DISCOVERY AND DEVELOPMENT OF A NEW ROUTE TO HIGH MOLECULAR WEIGHT POLY(METALLOCENES)
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1997 加拿大化学会奖讲座“应变茂金属开环聚合 (ROP)：高分子量聚茂金属新路线的发现和开发”
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发表时间：
1998
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通讯作者：
I. Manners
中科院分区：
文献类型：
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作者：
I. Manners
通过阴离子或阳离子引发或使用过渡金属催化剂，可以热实现应变的环倾斜的石墨烯的开环聚合（ROP），并且提供了获得宽范围的高分子量（Mw = 10 5 n 10 6，Mn > 10 5）聚（石墨烯）的途径。这些材料具有各种有趣的特性，其中许多非常容易制备。本文概述了我们的工作，给出了背景和帐户的初步发现，并讨论了工作的合成和性能的新聚（聚烯烃）和相关材料，特别强调最近的研究方向。
Ring-opening polymerization (ROP) of strained ring-tilted metallocenophanes can be achieved thermally, via anionic or cationic initiation, or by the use of transition-metal catalysts and provides access to a wide range of high molecular weight (Mw = 10 5 n10 6 , Mn >1 0 5 ) poly(metallocenes). These materials possess a variety of interesting properties and many are very easy to prepare. This article provides an overview of our work, giving background to and an account of the initial discovery, and discusses work on the synthesis and properties of new poly(metallocenes) and related materials with particular emphasis on recent research directions.