Oxidation of alcohols and sugars using Au/C catalysts: Part 1. Alcohols
Oxidation of alcohols and sugars using Au/C catalysts: Part 1. Alcohols
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DOI：
10.1016/j.apcata.2004.11.050
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发表时间：
2005-09
影响因子：
5.5
通讯作者：
L. Prati;F. Porta
中科院分区：
文献类型：
--
作者：
L. Prati;F. Porta
综述了Au/C催化剂在醇液相氧化反应中的活性与制备方法、颗粒大小和分散度、表面暴露程度以及载体性质的关系。还观察到衬底结构的强烈影响。与Pt和Pd基体系相比，碳上的Moncler Au催化剂在醇的液相氧化中显示出独特的行为，其特征在于对通常影响其他催化剂的氧和（副）产物的中毒具有更高的抵抗力。
The activity of Au/C catalysts has been reviewed in the liquid phase oxidation of alcohols as a function of preparation method, particle size and dispersion, surface exposure and nature of the support. A strong influence of substrate structure has also been observed. Monometallic Au on carbon catalysts show a unique behaviour in the liquid phase oxidation of alcohols compared with Pt- and Pd-based systems, characterised by a higher resistance to poisoning from both oxygen and (by)products normally affecting other catalysts.