Vapor pressures of aqueous 2-butoxyethanol solutions at 25.degree.C: transitions in mixing scheme

Vapor pressures of aqueous 2-butoxyethanol solutions at 25.degree.C: transitions in mixing scheme
复制标题

25°C 时 2-丁氧基乙醇水溶液的蒸气压:混合方案中的转变

DOI:
10.1021/j100163a041
复制
发表时间:
1991
期刊:
The Journal of Physical Chemistry
影响因子:
--
通讯作者:
Y. Koga
Y. Koga
中科院分区:
--
文献类型:
--
作者:
Y. Koga

文献摘要

被引文献

相似文献

测定了2-丁氧基乙醇(BE)水溶液在25.00 ℃时的蒸气压.用Boissonnas方法计算了BE和H2 O的分压,并由此计算了过量偏摩尔自由能G m E(i)(i=BE或H2 O).利用本实验室以前测得的过量偏摩尔熵HmE(i)(i=BE或H2O)计算了过量偏摩尔熵SmE(i)(i=BE或H2O)
The vapor pressures of aqueous solutions of 2-butoxyethanol (BE) were determined at 25.00 o C. The partial pressures of BE and H 2 O and hence the excess partial molar free energies, G m E (i) (i=BE or H 2 O) were calculated by the Boissonnas method. Using the values of the excess partial enthalpies, H m E (i) (i=BE or H 2 O), measured previously in this laboratory the excess partial molar entropies, S m E (i) (i=BE or H 2 O), were calculated