Surface-modified meso-carbon microbeads anode for dry polymer lithium-ion batteries

Surface-modified meso-carbon microbeads anode for dry polymer lithium-ion batteries
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DOI:
10.1016/j.jpowsour.2007.09.035
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发表时间:
2008-04-01
影响因子:
9.2
通讯作者:
Yamamoto, O.
Yamamoto, O.
中科院分区:
工程技术2区
文献类型:
--
作者:
Imanishi, N.;Ono, Y.;Yamamoto, O.

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在表面修饰的介孔碳微球(MCMB)中获得了高负极性能的干式聚合物锂离子电池。将MCMB和聚氯乙烯(PVC)混合物在700℃惰性气氛下加热6h。通过这种处理,MCMB的表面覆盖了来自聚氯乙烯热解的低结晶碳材料。表面修饰的MCMB电极在干式聚合物电解液中的可逆容量为300mAHg(-1),与液体电解液中的可逆容量相当。(C)2007 Elsevier B.V.保留所有权利。
A high-anode performance for dry polymer lithium-ion batteries was obtained in the surface-modified meso-carbon microbeads (MCMB). MCMB and polyvinylchloride (PVC) mixture was heated at 700 degrees C for 6 h under inert atmosphere. By this treatment, the surface of MCMB is covered with low-crystallin e carbon material derived from PVC pyrolysis. The surface-modified MCMB electrode applied to dry polymer electrolytes shows a reversible capacity of 300 mAh g(-1), which is comparable to those obtained in the liquid electrolyte systems. (C) 2007 Elsevier B.V. All rights reserved.