Conversion of a hydroperoxo complex, (TpiPr2)(py)Pd-OOH, into a cyclic alkylperoxo complex, [HB(pziPr2)2(pz-3-CMe2-5-i-Pr)](py)Pd-OO, catalyzed by Cu(II) species [TpiPr2:: Hydrotris(3,5-diisopropylpyrazolyl)borato]
Conversion of a hydroperoxo complex, (TpiPr2)(py)Pd-OOH, into a cyclic alkylperoxo complex, [HB(pziPr2)2(pz-3-CMe2-5-i-Pr)](py)Pd-OO, catalyzed by Cu(II) species [TpiPr2:: Hydrotris(3,5-diisopropylpyrazolyl)borato]
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DOI：
10.1246/cl.2003.486
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发表时间：
2003-06-05
影响因子：
1.6
通讯作者：
Akita, M
中科院分区：
文献类型：
--
作者：
Kujime, M;Hikichi, S;Akita, M
用催化量的Cu（II）物质处理氢过氧化钯配合物（Tp（iPr 2））（py）Pd-OOH，导致金属中心附近异丙基的次甲基部分过氧化，得到环状烷基过氧化钯配合物。
Treatment of a hydroperoxopalladium complex, (Tp(iPr2))(py)Pd-OOH, with a catalytic amount of a Cu(II) species resulted in peroxidation of the methine moiety of an isopropyl group proximal to the metal center to give a cyclic alkylperoxopalladium complex.