On-Demand Electrochemical Synthesis of Tetrakisacetonitrile Copper(I) Triflate and Its Application in the Aerobic Oxidation of Alcohols.
On-Demand Electrochemical Synthesis of Tetrakisacetonitrile Copper(I) Triflate and Its Application in the Aerobic Oxidation of Alcohols.
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DOI：
10.1021/acs.inorgchem.1c00488
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发表时间：
2021-04
影响因子：
4.6
通讯作者：
Thomas P. Nicholls;R. Bourne;B. Nguyen;N. Kapur;C. Willans
中科院分区：
文献类型：
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作者：
Thomas P. Nicholls;R. Bourne;B. Nguyen;N. Kapur;C. Willans
开发了在间歇和连续流动条件下按需电化学合成三氟甲磺酸铜(I)的方法。电化学方法的一个主要优点是反应的唯一副产物是氢气，这消除了后处理和纯化的需要，并且水不会掺入产物中。电化学合成完成后，溶液直接转移或分配到反应混合物中，用于苯甲醇的催化氧化，无需后处理或纯化。
An on-demand electrochemical synthesis of copper(I) triflate under both batch and continuous flow conditions has been developed. A major benefit of the electrochemical methodology is that the only byproduct of the reaction is hydrogen gas, which obviates the need for workup and purification, and water is not incorporated into the product. Upon completion of the electrochemical synthesis, solutions are directly transferred or dispensed into reaction mixtures for the catalytic oxidation of benzyl alcohol with no requirement for workup or purification.