Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands
Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands
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DOI：
10.1002/chem.200903118
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发表时间：
2010-01-01
影响因子：
4.3
通讯作者：
Nishiyama, Hisao
中科院分区：
文献类型：
--
作者：
Inagaki, Tomohiko;Phong, Le Thanh;Nishiyama, Hisao
手性双(恶唑啉基苯基)胺被证明是铁和钴催化剂的有效辅助配体，对酮的不对称氢化硅烷化和烯酮的不对称共轭氢化硅烷化具有高活性。
Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.