Precise and accurate isotope fractionation factors (α17O, α18O and αD) for water and CaSO4•2H2O (gypsum)

Precise and accurate isotope fractionation factors (α17O, α18O and αD) for water and CaSO4•2H2O (gypsum)
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DOI:
10.1016/j.gca.2016.11.001
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发表时间:
2017-02-01
影响因子:
5
通讯作者:
Hodell, David A.
Hodell, David A.
中科院分区:
地球科学1区
文献类型:
--
作者:
Gazquez, Fernando;Evans, Nicholas P.;Hodell, David A.

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石膏(CaSO 4中心点2 H(2)O)是一种含有结晶水的水合矿物,也称为石膏水合水(GHW)。我们确定了同位素分馏因子(α O-17,α O-18和α D)之间的GHW和自由水的母液在温度范围从3摄氏度到55摄氏度在不同的盐度和沉淀率。氢同位素分馏因子(α D石膏-水)在3 ℃和55 ℃之间每℃增加0.0001单位,
Gypsum (CaSO4 center dot 2H(2)O) is a hydrated mineral containing crystallization water, also known as gypsum hydration water (GHW). We determined isotope fractionation factors (alpha O-17, alpha O-18 and alpha D) between GHW and free water of the mother solution in the temperature range from 3 degrees C to 55 degrees C at different salinities and precipitation rates. The hydrogen isotope fractionation factor (alpha Dgypsum-water) increases by 0.0001 units per degrees C between 3 degrees C and 55 degrees C and salinities