Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site.
Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site.
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DOI：
10.1039/b712805c
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发表时间：
2008-01
影响因子：
4.9
通讯作者：
Fenfen Xu;C. Tard;Xiufeng Wang;S. Ibrahim;D. Hughes;W. Zhong;X.-R. Zeng;Q. Luo;Xiaoming Liu-Xiaoming
中科院分区：
文献类型：
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作者：
Fenfen Xu;C. Tard;Xiufeng Wang;S. Ibrahim;D. Hughes;W. Zhong;X.-R. Zeng;Q. Luo;Xiaoming Liu-Xiaoming
通过在双铁位点位移垂坠的半不稳定配体的一氧化碳结合可以通过配体质子化途径基本上“打开”，这与金属-金属键质子化是竞争的。
Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially 'switched-on' via a ligand protonation pathway which is competitive with metal-metal bond protonation.