The first total synthesis and structural determination of actinopyrone A
The first total synthesis and structural determination of actinopyrone A
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DOI：
10.1016/j.tetlet.2006.05.028
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发表时间：
2006-07-24
影响因子：
1.8
通讯作者：
Tatsuta, Kuniaki
中科院分区：
文献类型：
--
作者：
Hosokawa, Seijiro;Yokota, Kazuya;Tatsuta, Kuniaki
通过我们开发的远程立体诱导、Kocienski烯化、Horner-Wadsworth-Emmons烯化和乙烯基吡喃酮的还原性去共轭，合成了放线吡喃酮A（1）。还建立了一种简便的O-甲基化方法来制备γ-吡喃酮。(c)2006爱思唯尔有限公司版权所有。
Actinopyrone A (1) has been synthesized by using our developed remote stereoinduction, Kocienski olefination, Horner-Wadsworth-Emmons olefination, and reductive de-conjugation of the vinylpyrone. A concise method of O-methylation to obtain the gamma-pyrone has also been established. (c) 2006 Elsevier Ltd. All rights reserved.