Dynamic and fluorescent nanoscale phenanthroline/terpyridine zinc(II) ladders.: Self-recognition in unlike ligand/like metal coordination scenarios
Dynamic and fluorescent nanoscale phenanthroline/terpyridine zinc(II) ladders.: Self-recognition in unlike ligand/like metal coordination scenarios
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DOI：
10.1021/ja0525096
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发表时间：
2005-08-24
影响因子：
15
通讯作者：
Bats, JW
中科院分区：
文献类型：
--
作者：
Schmittel, M;Kalsani, V;Bats, JW
介绍了一种新的配位试剂盒，HETTAP方法，它允许以基本定量的产率制备超分子杂感金属邻菲咯啉/三联吡啶架子和梯子。由于纳米阶梯结构的动态性质，实现了两步双金属置换和类似金属/不同配位识别的场景。
A new coordination kit, the HETTAP approach, is described, which allows one to prepare supramolecular heteroleptic metal phenanthroline/terpyridine racks and ladders in basically quantitative yield. Due to the dynamic nature of the nanoladder structures, a two-step double-transmetalation and scenarios withlikemetal/unlikeligand recognition were realized.