Hydrothermal crystal growth of the high-pressure phases of α-PbO2 and TiO2 II

Hydrothermal crystal growth of the high-pressure phases of α-PbO2 and TiO2 II
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α-PbO2 和 TiO2 II 高压相的水热晶体生长

DOI:
10.1016/j.jallcom.2004.01.033
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发表时间:
2004
影响因子:
6.2
通讯作者:
N. Bendeliani
N. Bendeliani
中科院分区:
材料科学2区
文献类型:
--
作者:
T. I. Dyuzheva;L. Lityagina;N. Bendeliani

文献摘要

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在水热条件下生长了α-PbO 2和TiO 2 II高压相单晶。在p=4GPa,T=300-600°C条件下,得到深棕色二氧化铅晶体,尺寸约为0.25 mm × 0.25 mm ×0.65 mm。在p=9-9.5GPa和T=600-900°C条件下生长出透明、无色的二氧化钛晶体,尺寸约为0.03 mm ×0.03 mm ×0.15 mm。两种化合物的晶体形态。
Single crystals of high-pressure phases of α-PbO2and TiO2II were grown under hydrothermal conditions. Dark brown crystals of lead dioxide with a size of about 0.25 mm ×0.25 mm ×0.65 mm were obtained at p=4GPa and T=300–600°C. Transparent, colorless crystals of titanium dioxide with a size of about 0.03 mm ×0.03 mm ×0.15 mm were grown at p=9–9.5GPa and T=600–900°C. Crystal morphology is presented for both compounds.