pH Influenced molecular switching with micelle bound cavitands
pH Influenced molecular switching with micelle bound cavitands
复制标题
DOI：
10.1039/c1cc12901e
复制
发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Schramm, Michael P.
中科院分区：
文献类型：
--
作者：
Kim, Yeon Joo;Lek, Mark T.;Schramm, Michael P.
一系列间苯二酚芳烃宿主-两亲性客体配合物已经被开发出来，其中客体在宿主中的取向受到ph值的极大影响。客体附加一个三甲基铵和一个叔丁基，以响应空腔和宿主中负电荷的积累，将取向转换180度。
A series of resorcinarene host-amphiphilic guest complexes have been developed where guest orientation in the host is drastically influenced by pH. Guests appended with a trimethylammonium and a tert-butyl group switch orientation by 180 degrees in response to a buildup of negative charge in the cavitand host.