A STUDY OF THE SYSTEM HYDROGEN CHILORIDE AND WATER.
A STUDY OF THE SYSTEM HYDROGEN CHILORIDE AND WATER.
复制标题
氯化氢和水系统的研究。
DOI：
10.1021/ja01938a001
复制
发表时间：
1909
影响因子：
15
通讯作者：
F. F. Rupert
中科院分区：
文献类型：
--
作者：
F. F. Rupert
蒸汽压为一个大气压或更低的盐酸溶液的性质已经得到了相当充分的研究。已经进行了许多密度测定;已知密度的最浓溶液含有44.35%的氯化氢。蒸汽压、沸点和其他性质已测定到大约相同的百分比。皮克林发现了浓度从0到48.8%的氯化氢溶液的凝固点。他的凝固点曲线（作为本文末尾的一部分复制）表明存在两种固体水合物，即二水合物，含50.31%氯化氢，熔点-17.70;和三水合物，含40.33%氯化氢，熔点-24.4。前者由Pierre和Puchot于1876年制备并分离，而后者由Pickering发现并分析。溴化氢溴化氢的一水合物，HBr H2O是已知的，并且本研究的最初目的是确定固体一水合物HCl是否。可以得到H2O。
The properties of hydrochloric acid solutions whose vapor pressure is one atmosphere or less have been quite fully studied. Numerous density determinations havebeen made; the mostconcentrated solution of which the density is known contains 44.35 per cent, hydrogen chloride. 1 The vapor pressures, boiling points and other properties have been de-termined up to about the same percentage. Pickering found the freezing points of solutions of concentrations ranging from o to 48.8 per cent, hydrogen chloride. His freezing point curve, which is copied as part of the one at the end ofthis paper, shows the existence of two solid hydrates, namely the dihydrate, containing 50.31 per cent, hydrogen chloride, and melting at—17.70; and the trihydrate, containing 40.33 per cent, hy-drogen chloride, and melting at—24.4 o. The former had been prepared and isolated by Pierre and Puchot2 in 1876, while the latter was discovered and analyzed by Pickering. A monohydrateof hydrogen bromide, HBr. H20 is known, and the original purpose of thisinvestigation was to determine whether the solid monohydrate, HC1. H20 can be obtained.