Manganese-Cerium Porphyrin Tri-nuclear Complex as a Catalyst for Water Oxidation
Manganese-Cerium Porphyrin Tri-nuclear Complex as a Catalyst for Water Oxidation
复制标题
锰-铈卟啉三核配合物作为水氧化催化剂
DOI：
10.1080/713738661
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发表时间：
2002
影响因子：
0.7
通讯作者：
T. Imaoka
中科院分区：
文献类型：
--
作者：
Kimihisa Yamamoto;Shinsuke Nakazawa;T. Imaoka
采用本体电解法将水氧化成O2.作为氧化的催化剂，评价了铈双层德克尔卟啉作为电子介体的效果。当Ce（TCPP）2作为催化剂加入到MnTPPS-MnTPPS-MnTMPyP中时，观察到最佳性能。4-水双核锰卟啉双层德克尔铈卟啉多核配合物的电子氧化
The oxidation of water to O 2 was carried out by bulk electrolysis. As a catalyst for the oxidation, the effect of cerium double decker porphyrin as an electron mediator was evaluated. The best performance was observed when the Ce(TCPP) 2 was added to the MnTPPS-MnTPPS-MnTMPyP as a catalyst. 4-electron oxidation of water dinuclear Mn-porphyrin double decker cerium porphyrin multi-nuclear complex