Wetting properties of acrylic polymers containing perfluoro‐t‐butyl side chains
Wetting properties of acrylic polymers containing perfluoro‐t‐butyl side chains
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DOI：
10.1002/pol.1972.110100703
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发表时间：
1972-07
期刊：
影响因子：
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通讯作者：
J. Roitman;A. Pittman
中科院分区：
文献类型：
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作者：
J. Roitman;A. Pittman
尽管已经制备了许多含有氟化侧链的聚合物并检查了它们的润湿性能，但还没有出现含有全氟叔丁基的聚合物的报道。由于已知的最低能量表面 (1) 归因于填充良好的三氟甲基基团（全氟羧酸单层），因此研究全氟叔丁基基团的润湿行为很有意义，因为其外部仅由三氟甲基基团组成。我们制备并研究了全氟叔丁醇丙烯酸酯。
Although numerous polymers containing fluorinated side chains have been prepared and their wetting properties examined, no reports of polymers containing the perfluoro-t-butyl group have appeared. Because the lowest energy surfaces known (1) are attributed to well-packed trifluoromethyl groups (monolayers of perfluorocarboxylic acids), it was of interest to examine the wetting behavior of the perfluoro-t-butyl group, since its exterior is comprised solely of trifluoromethyl groups. We have prepared and studied acrylic esters of perfluoro-t-butyl alcohol.