STRUCTURAL COMPARISON OF OXOBIS(BENZENE-1,2-DITHIOLATO)MOLYBDENUM-(V) AND OXOBIS(BENZENE-1,2-DITHIOLATO)MOLYBDENUM-(IV) COMPLEXES
STRUCTURAL COMPARISON OF OXOBIS(BENZENE-1,2-DITHIOLATO)MOLYBDENUM-(V) AND OXOBIS(BENZENE-1,2-DITHIOLATO)MOLYBDENUM-(IV) COMPLEXES
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DOI：
10.1039/c39860001541
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发表时间：
1986-10-15
影响因子：
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通讯作者：
CLEGG, W
中科院分区：
文献类型：
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作者：
BOYDE, S;ELLIS, SR;CLEGG, W
二甲基甲酰胺溶液中的 [MoO(bdt)2]–/[MoO(bdt)2]2–(H2bdt = 苯-1,2-二硫醇) 氧化还原对在 E½=–350 mV（相对于标准甘汞电极）下是完全可逆的过程，并且这些阴离子均已通过 X 射线晶体学进行了表征；前者的金属-配体键长略短于后者，MoV-O = 1.668(3)Å，MoIV–O = 1.699(6)Å，平均MoV–S = 2.377(1)Å，MoIV–S = 2.388(2)Å。
The [MoO(bdt)2]–/[MoO(bdt)2]2–(H2bdt = benzene-1,2-dithiol) redox couple, in dimethylformamide solution, is a fully reversible process at E½=–350 mV vs. standard calomel electrode and each of these anions has been characterised by X-ray crystallography; the metal–ligand bond lengths of the former are slightly shorter than those of the latter, MoV-O = 1.668(3)Å, MoIV–O = 1.699(6)Å, mean MoV–S = 2.377(1)Å, MoIV–S = 2.388(2)Å.