Phosphorus- and boron-doped hydrogenated amorphous silicon films prepared using vaporized liquid cyclopentasilane

Phosphorus- and boron-doped hydrogenated amorphous silicon films prepared using vaporized liquid cyclopentasilane
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DOI:
10.1016/j.tsf.2015.05.040
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发表时间:
2015-08-31
期刊:
影响因子:
2.1
通讯作者:
Shimoda, Tatsuya
Shimoda, Tatsuya
中科院分区:
材料科学3区
文献类型:
--
作者:
Masuda, Takashi;Takagishi, Hideyuki;Shimoda, Tatsuya

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A simple, inexpensive method for fabricating a hydrogenated amorphous silicon (a-Si: H) film using thermal chemical vapor deposition from cyclopentasilane (CPS) at atmospheric pressure with a substrate temperature of 370 degrees C is described. The reactant gas was generated from liquid CPS by vaporization in the deposition chamber. The vaporized CPS gas was transformed immediately into a-Si: H film on a heated substrate. The a-Si: H films could be doped either n- or p-type by dissolving appropriate amounts of white phosphorus or decaborane, respectively, in the liquid CPS before vaporization. This process allows deposition of doped a-Si: H films of photovoltaic device-quality without the need for handling, storage, or transportation of large amounts of gaseous reactants. (C) 2015 Elsevier B.V. All rights reserved.