Cationic crown ether complexes of germanium(II).
Cationic crown ether complexes of germanium(II).
复制标题
锗(II)的阳离子冠醚配合物。
DOI:
10.1002/anie.200901351
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发表时间:
2009
影响因子:
--
通讯作者:
K. Baines
中科院分区:
文献类型:
--
作者:
P. Rupar;Rajoshree Bandyopadhyay;Benjamin F Cooper;Michael R Stinchcombe;P. Ragogna;C. L. Macdonald;K. Baines
Fit for a king: Cationic complexes of Ge(II) can be prepared by using crown ethers to stabilize and protect the germanium center. Three different crown ethers were employed: [12]crown-4 (see structure, Ge teal, O red, C gray), [15]crown-5, and [18]crown-6. The structures of the cationic complexes depend on the cavity size of the crown ether and on the substituent on germanium.