Self-assembled reversed bilayers directed by pnictogen bonding to form vesicles in solution.
Self-assembled reversed bilayers directed by pnictogen bonding to form vesicles in solution.
复制标题
通过磷元素键合引导自组装反向双层，在溶液中形成囊泡。
DOI：
10.1039/c8cc05187a
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发表时间：
2018
影响因子：
4.9
通讯作者：
Anthony F. Cozzolino
中科院分区：
文献类型：
--
作者：
Shiva Moaven;Jingze Yu;M. Vega;D. Unruh;Anthony F. Cozzolino
人工囊泡可以帮助研究和理解生物细胞膜。这项研究采用磷元素键合来主动引导真正的反向双层的自组装。通过多个强 SbO 相互作用自组装的锑(iii)醇盐笼在二维中传播，形成固态的反向双层结构。长烷基尾使这些反向双层能够在溶液中加工成与生物细胞膜相反的囊泡。
Artificial vesicles can aid in the study and understanding of biological cell membranes. This study employs pnictogen bonding to actively direct the self-assembly of a true reversed bilayer. Antimony(iii) alkoxide cages that self-assemble through multiple strong SbO interactions propagate in two dimensions to form a reverse bilayer structure in the solid state. Long alkyl tails allow these reverse bilayers to be processed into vesicles in solution that are a reverse of biological cell membranes.
影响因子：
16
作者：
Lener T;Gimona M;Aigner L;Börger V;Buzas E;Camussi G;Chaput N;Chatterjee D;Court FA;Del Portillo HA;O'Driscoll L;Fais S;Falcon-Perez JM;Felderhoff-Mueser U;Fraile L;Gho YS;Görgens A;Gupta RC;Hendrix A;Hermann DM;Hill AF;Hochberg F;Horn PA;de Kleijn D;Kordelas L;Kramer BW;Krämer-Albers EM;Laner-Plamberger S;Laitinen S;Leonardi T;Lorenowicz MJ;Lim SK;Lötvall J;Maguire CA;Marcilla A;Nazarenko I;Ochiya T;Patel T;Pedersen S;Pocsfalvi G;Pluchino S;Quesenberry P;Reischl IG;Rivera FJ;Sanzenbacher R;Schallmoser K;Slaper-Cortenbach I;Strunk D;Tonn T;Vader P;van Balkom BW;Wauben M;Andaloussi SE;Théry C;Rohde E;Giebel B
通讯作者：
Giebel B