Two-carbon ring expansion of cyclobutanone skeletons by nickel-catalyzed intermolecular alkyne insertion
Two-carbon ring expansion of cyclobutanone skeletons by nickel-catalyzed intermolecular alkyne insertion
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DOI：
10.1016/j.tet.2006.03.118
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发表时间：
2006-08-07
期刊：
影响因子：
2.1
通讯作者：
Matsuda, Takanori
中科院分区：
文献类型：
--
作者：
Murakami, Masahiro;Ashida, Shinji;Matsuda, Takanori
环丁酮与炔在镍（0）催化剂存在下的反应形式上实现了环丁酮的羰基碳和α-碳之间的分子间炔插入，提供了六元碳环骨架。(c)2006爱思唯尔有限公司版权所有。
The reaction of cyclobutanone with an alkyne in the presence of a nickel(0) catalyst formally achieves intermolecular alkyne insertion between the carbonyl carbon and the a-carbon of a cyclobutanone, providing a six-membered carbocyclic skeleton. (c) 2006 Elsevier Ltd. All rights reserved.