Profound isotope effect in dissociation of triatomic hydrogen.
Profound isotope effect in dissociation of triatomic hydrogen.
复制标题
三原子氢离解中的深刻同位素效应
DOI:
10.1021/jp312560t
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发表时间:
2013
期刊:
影响因子:
--
通讯作者:
H. Helm
中科院分区:
文献类型:
--
作者:
P. C. Fechner;K. Mozer;H. Helm
Three-particle dissociation of high-lying Rydberg states of D3is induced by an external electric field. We observe that the momentum vector correlation map of the center-of-mass motion of the fragments converges near the ionization threshold to two distinct fragment configurations, the near linear geometry and the symmetric acute angle geometry. A comparison is made with the momentum vector correlation map recorded in dissociative recombination of D3+with slow electrons and with the corresponding results for H3where the acute angle geometry is conspicuously absent.
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