Preparation of Nb-Cr Alloy Powder by Hydrogenation

Preparation of Nb-Cr Alloy Powder by Hydrogenation
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加氢法制备铌铬合金粉末

DOI:
10.2320/jinstmet1952.62.7_681
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发表时间:
1998
影响因子:
--
通讯作者:
S. Hanada
S. Hanada
中科院分区:
材料科学4区
文献类型:
--
作者:
M. Kosuge;H. Hosoda;S. Hanada

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The pulverization by hydrogenation is a new method for fa’bricating intermetallic powders with high quality and low cost. In this study, the pulverization by hydrogenation was studied for various Nb−Cr alloys. The hydrogenation was performed under the hydrogen atmosphere of O.1 MPa in an arc−melting chamber without exposure to air after arc−melting. Constituent phases and lattice constants before and after hydrogenation were examined by X−ray diffraction analysis. It is found that the pulverization by hydrogenation occurs only in two phase a皿oys consisting of Nb solid solution(Nbss)and NbCr2. In the Nbss/NbCr2 alloys, the lattice constant of Nbs, increases remarkably through hydrogenation, while that of NbCr2 does not change. It is concluded that the pulverization of the Nbss/NbCr2 two phase alloy is caused by large strain accompanied with lattice expansion of Nbs, through hydrogenation and crack nucleation at intrinsically brittle NbCr2.