A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity
A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity
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DOI：
10.1021/ja063538z
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发表时间：
2006-09-13
影响因子：
15
通讯作者：
Zhou, Hong-Cai
中科院分区：
文献类型：
--
作者：
Ma, Shengqian;Zhou, Hong-Cai
合成了一种含有内嵌金属中心的金属-有机骨架PCN-9，并对其进行了晶体学表征。PCN-9的h2h和ch4吸附焓是目前报道的最高的。
A metal−organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2and CH4adsorption enthalpies of PCN-9 are among the highest reported thus far.