Carbon-carbon bond formation in glycolic acid generated spontaneously from dichloromethane in hot water

Carbon-carbon bond formation in glycolic acid generated spontaneously from dichloromethane in hot water
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DOI:
10.1246/cl.2004.302
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发表时间:
2004-02
期刊:
影响因子:
1.6
通讯作者:
Chihiro Wakai;Saiko Morooka;N. Matubayasi;M. Nakahara
Chihiro Wakai;Saiko Morooka;N. Matubayasi;M. Nakahara
中科院分区:
化学4区
文献类型:
--
作者:
Chihiro Wakai;Saiko Morooka;N. Matubayasi;M. Nakahara

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Hydrothermal reaction of dichloromethane (CH2Cl2) at 1 mol/dm3 leads to the formation of glycolic acid without metal catalysts at temperatures of 200–250 °C. The reaction consists of three steps. F...