Simplified synthesis of decaborane(14) from sodium tetrahydroborate via tetradecahydroundecaborate(1-) ion
Simplified synthesis of decaborane(14) from sodium tetrahydroborate via tetradecahydroundecaborate(1-) ion
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通过十四氢十一硼酸根 (1-) 离子从四氢硼酸钠简化合成十硼烷 (14)
DOI：
10.1021/ic50220a015
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发表时间：
1981
影响因子：
4.6
通讯作者：
P. Remec
中科院分区：
文献类型：
--
作者：
G. B. Dunks;K. Barker;E. Hedaya;Catherine. Hefner;Kathy. Palmer;P. Remec
前面描述了由BF 3 O（C2 H5）2和NaBH 4容易地合成十四氢十一硼酸根（1-）离子BnH 14-。2.重铬酸钠氧化所制备的BUH 14“离子水溶液得到的主要中性产物是癸硼烷（14），B10 H14。因此，B10 H14首次通过一种可以在标准实验室设备中进行的相对低成本的程序而普遍可用。
Introduction A facile synthesis of tetradecahydroundecaborate (l-) ion, BnH14", from BF3O (C2H5) 2 and NaBH4 was previously described. 2 The major neutral product obtained from the sodium dichromate oxidation of an aqueous solution of BUH14 “ion so prepared was decaborane (14), B10H14. 3 Thus B10H14 was made generally availablefor the first time by a relatively low-cost procedure which can be performed in standard laboratory apparatus.