PhI-catalyzed α-tosyloxylation of ketones with m-chloroperbenzoic acid and p-toluenesulfonic acid

PhI-catalyzed α-tosyloxylation of ketones with m-chloroperbenzoic acid and p-toluenesulfonic acid
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DOI:
10.1055/s-2006-933120
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发表时间:
2006-03
期刊:
影响因子:
2
通讯作者:
Yuki Yamamoto;H. Togo
Yuki Yamamoto;H. Togo
中科院分区:
化学4区
文献类型:
--
作者:
Yuki Yamamoto;H. Togo

文献摘要

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以间氯过苯甲酸和对甲苯磺酸为原料,在催化量的碘苯存在下,升温反应合成了多种α-对甲苯磺酰氧基酮。
Various α-tosyloxyketones were efficiently prepared in high yields from the reaction of ketones with m-chloroperbenzoic acid and p-toluenesulfonic acid in the presence of a catalytic amount of iodobenzene at warming temperature.