Observation of Sequential Electrophilic Substitution of Bromothiophene and Immediate Reductive Elimination of Arylpalladium Complexes
Observation of Sequential Electrophilic Substitution of Bromothiophene and Immediate Reductive Elimination of Arylpalladium Complexes
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DOI：
10.1246/cl.2006.1100
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发表时间：
2006-09
影响因子：
1.6
通讯作者：
A. Sugie;Kei Kobayashi;Yuji Suzaki;K. Osakada;A. Mori
中科院分区：
文献类型：
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作者：
A. Sugie;Kei Kobayashi;Yuji Suzaki;K. Osakada;A. Mori
芳基(碘)钯(Ⅱ)配合物与2，3-二溴噻吩在硝酸银/氟化钾存在下的反应，以甲酰化反应，产率为-78%。这些结果表明，帕拉迪乌是一种有效的生物材料。
The reaction of aryl(iodo)palladium(II)(bpy) complex with 2,3-dibromothiophene in the presence of AgNO3/KF as an activator induces CH arylation in 64–78% yields. These results suggest that palladiu...