[VIII(H2O)]3O(O2CC6H4CO2)3•(Cl, 9H2O) (MIL-59):: a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework
[VIII(H2O)]3O(O2CC6H4CO2)3•(Cl, 9H2O) (MIL-59):: a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework
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DOI：
10.1039/b202749f
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发表时间：
2002-01-01
影响因子：
4.9
通讯作者：
Férey, G
中科院分区：
文献类型：
--
作者：
Barthelet, K;Riou, D;Férey, G
[V-III（H2O）]（3）O（O2CC6H4CO2）（3）. (Cl 9 H（2）O）（表示为MIL-59）呈现了由八面体钒三聚体通过螯合阴离子连接体连接而形成的三维框架，以界定其中水分子和氯阴离子被封闭的笼;讨论了MIL-59的受抑磁性行为。
[V-III (H2O)](3)O(O2CC6H4CO2)(3).(Cl, 9H(2)O) (denoted MIL-59) presents a three-dimensional framework built up from octahedral vanadium trimers joined via the isophthalate anionic linkers to delimit cages where water molecules and chlorine anions are occluded; the frustrated magnetic behaviour of MIL-59 is discussed.